Science & Research
NOTE: All information on this page is taken
from the National Caves Association website and only
used as an educational guide. If you would
like more information, please visit the National
Caves Association's website at
www.cavern.com/cave-science.
It is not within the scope of this website to
discuss the specific geologic history for each cave
within the National Cave Association. While the
geology can differ radically between caves, the
basic science behind how caves form remains somewhat
constant.
WHAT IS KARST?
A map showing the density of caves by county
within the United States reveals that, for the most
part, caves are located within specific areas or
regions. Many of these regions share some
similarities in the type of rock within the area as
well as how water flows through the region. These
regions where caves form often develop a “look” to
the landscape which actually has a name. The name
for such landscapes is karst.
KARST LANDSCAPES
Karst landscapes may be characterized by the
presence of sinkholes/dolines, disappearing streams,
closed basins, caves, and pits. Another important
factor for a karst landscape is subterranean
drainage. There need not be limestone within a karst
landscape, but the rock generally does need to be
soluble. Within the United States, 20% of the land
surface is karst.
KARST & AQUIFERS
Another common feature of karst landscapes is the
presence of an aquifer. Think of an aquifer like a
huge bucket of water lying under the ground. This
bucket is filled with water. Springs on the surface
would be similar to holes in the bucket – water
flows out wherever the water table intersects the
surface. Wells would be similar to giant drinking
straws stuck into the bucket. By sucking on the
straws (pumping on the wells), we draw water out of
the aquifer. The water leaving the aquifer will
lower the water table.
So how does the water get into the aquifer?
Gravity is doing a good bit of the work. As rain
falls on the surface, the water will seep into the
ground. Some of that water will run off on the
surface to fill up creeks, rivers, ponds, or lakes.
Some of the water will soak into the soil but will
be utilized by plants or animals and will not get
very far underground. The rest of the water will get
past the surface and past the plants and start
making its way deeper into the earth.
While water is passing through the rock, it will
also move through two distinct areas or zones within
the aquifer. The first zone the water passes through
is called the zone of aeration. This is the area
above the water table where the majority of pores or
spaces within the rock are filled mostly with air.
The next zone where the water passes through is
called the zone of saturation. This is the area
under the water table where the rock is completely
saturated with water. Between these two layers is
the capillary fringe. A capillary is similar to a
very small drinking straw. The capillary fringe is
the boundary where the attractive forces between the
molecules of water and rock will cause the rock to
“suck” up water into the “straw,” thus forming the
capillary fringe.
What does this have to do with caves? The cave
passages containing air would be within the zone of
aeration. The zone of saturation falls somewhere
below these passages. Cave forming processes may
occur within any of these zones, wherever water has
been flowing. But there is some chemistry involved
in how caves form.
CAVE CHEMISTRY
While it is true that some caves can be formed by
the action of waves (sea caves) or even lava (lava
tubes), we will deal with those caves formed by
water dissolving rock or solution caves. The term
dissolution refers to the chemical weathering or
“dissolving” of limestone or other soluble rocks by
water. Water, by itself and with enough time, could
eventually carve out a small opening in rock. For a
large cave system to form, however, water needs some
additional help, which it gets from acids within the
water. We will discuss two types of acids, carbonic
and sulfuric, which are common in some types of
groundwater. We will then discuss how these acids
form caves.
CARBONIC ACID, SULFURIC ACID & CAVES
As rain falls through the atmosphere, and
especially as it moves through the soil, the water
mixes with carbon dioxide gas to create a weak
solution of carbonic acid. This acid is many times
more efficient than water at dissolving rock. An
even more powerful acid to dissolve rock is sulfuric
acid. This acid can be formed either by water coming
into contact with rocks containing sulfide minerals,
or by bacteria within the groundwater which break
down rock as a normal process of their life cycle.
But even a weak solution of carbonic acid, or the
much stronger sulfuric acid, will not make a cave
unless it can get underground. One way water moves
deeper into the earth is through cracks or fractures
which geologists call joints or faults. These
fractures allow water to move further into the rock.
The fractures widened over time as the acid
dissolved away the soluble rock. What once were
small cracks eventually widened into larger voids or
cavities. Some of these cavities widened into larger
rooms or caves. And some of the caves eventually
connected with other caves to form caverns.
CAVE FORMATIONS
Up to this point, we’ve discussed karst,
aquifers, and acids, all of which contribute to the
formation of a cave or cavern. But what about the
cave formations – the stalactites, stalagmites, soda
straws, fried eggs, bacon, flowstone, and many other
types of speleothems? These formations are created
by a process which involves three steps.
First, and as explained above with carbonic acid
and caves, as rain passes through the soil layers,
it will mix with carbon dioxide gas. The carbon
dioxide gets in the soil from decaying plant and
animal remains. A weak solution of carbonic acid is
formed from this mixing. As the mixture moves toward
the cave, the acids in the water will dissolve
minerals from the rock through which it passes.
These minerals are carried within the solution and
into the cave.
A great deal of a cave’s chemistry is driven by
equilibrium – all things must be equal. When they
aren’t equal, then that’s when things happen. In the
case of water, once the solution reaches any cavity
filled with air, a number of different things can
happen. One thing is that the amount of carbon
dioxide carried by the water will often be higher
than the air within the cave. If this is the case,
the water’s carbon dioxide will be released to the
cave air in an effort to equilibrate between the
two. When the carbon dioxide gets released, the
solution must also deposit some of the dissolved
minerals. This mineral deposition is what forms all
of the different cave formations.
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